氢氧化钠与硫酸铜反应能不能生成氧化铜硫酸和硫酸铜的混合溶液和氢氧化钠氢钠?


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不同组份出现的不同现象...
不同组份出现的不同现象
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展开全部反应结果:1、完全沉淀(PH=6~7)反应式:2NaOH+CuSO4=Cu(OH)2↓+Na2SO4此时,硫酸铜与氢氧化钠物质的量之比近似1:2。所得反应产物为蓝色絮奖沉淀,久置后上层溶液无色,即生成氢氧化铜沉淀与水。2、硫酸铜过量(PH值<6)反应式:4CuSO4+6NaOH=Cu4(OH)6SO4+3Na2SO4在试管内装1/3体积的硫酸铜后,滴入4~5滴氢氧化钠溶液,生成兰绿色块状沉淀。溶液久置后呈蓝色,经查证,兰绿色沉淀即为碱式硫酸铜。3、氢氧化钠过量(PH>7)反应式:4NaOH+CuSO4=Na2[Ca(OH)4]↓+Na2SO4我们在装了1/3试管的氢氧化钠后再滴入3~4滴硫酸铜溶液。久置后,上呈无色,而沉淀层为一种蓝白杂泪的糊状沉淀,此为铜酸钠。生成原因及生成物性质1、氢氧化铜[Cu(OH)2]这是实验最简单的结果,生成原因是一个铜离子正好与两个氢氧化铜。其为一种蓝色固体。难溶于水,加热易分解,微显两性。2、碱式硫酸铜。[Cu4(OH)6SO4]在实验中,氢氧化钠处于不足,故氢氧离子相对铜离子也就不足,使氢氧根离子无法完全结合所有铜离子,故它代替一部分硫酸根离子,生成碱式硫酸铜。这是一种兰绿色固体,受热可分解(生成硫酸铜和氢氧化铜),但受热时间比氢氧化钠分解的时间还要长,生成蓝色与黑色并存浊液[Cu4(OH)6SO4=CuSO4+3Cu(OH)2,Cu(OH)2=CuO+H2O]并且,碱式硫酸铜可溶于无机酸(实验用盐酸和稀硫酸),有机酸(实验用苯酚和乙酸),碱(实验用氢氧化钠和氢氧化钙)等。它还会与氨水反应,生成钢蓝色溶液,有氨味[Cu4(OH)6SO4+8NH3=3Cu(NH3)2(OH)2+Cu(NH3)2SO4]3、铜酸钠[Na2Cu(OH)4]它的形成原因相当复杂,删繁就简地就是氢氧与铜离子结合成氢氧化铜后,由于溶液中氢所氧根偏多,而氢氧化铜又微显两性(氢氧化铜可写为Cu(OH)2及H2CuO2)故又结合两个氢氧根离子,再与钠离子结合生成铜酸钠。这是一种相当不稳定的蓝白色物质,难溶于水,它只有在碱性条件下才能存在,溶液稀释后,它即分解成氢氧化铜和氢氧化钠[Na2Cu(OH)4=2NaOH+CU(OH)2↓],在久置之后,它会风化分解[Na2Cu(OH)4=2NaOH+CU(OH)2↓]。它会与酸反应,例如与稀盐酸反应生成氧气与钠盐,与浓盐酸反应生成氯气和氧气。已赞过已踩过你对这个回答的评价是?评论
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展开全部生成蓝色絮状沉淀。展开全部我想想反应后生成蓝色絮状沉淀 也就是Cu(OH)2
Cu(OH)2属于不溶性的金属氢氧化物,受热分解为对应价态的氧化物和水
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